A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwave assisted transesterification onestep was carried out. Pdf production of biodiesel from waste vegetable oil. Free fatty acids will increase the time required for heating vegetable oil. Sep 02, 2015 mcc alt fuels presents videos aimed at technicians who service vehicles that run on alternative fuels. The new process technologies developed during the last years made it possible to produce biodiesel from recycled frying oils comparable in quality to that of virgin vegetable oil biodiesel with an added attractive advantage of being. Production optimization and quality assessment of biodiesel from. However, in manausam there is no production of biodiesel at industrial scale, because. Recent trends in biodiesel production biofuel research journal. Oilseed plants are used for the production of biodiesel through the process called transesterification reaction which is a process by which alcohol reacts with vegetable oil in the presence of. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out. Biodiesel is a type of fuel prepared by changing vegetable oil, animal fat, special types of algae and possibly even sewage. The manufacture of biodiesel from the used vegetable oil uni kassel. Biodiesel production is based on the transesterification reaction of vegetable.
Preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used. Waste food oil can be obtained from any restaurant or dining hall that uses vegetable oil for frying food. Solid base from alkalized sbc ash had basic sites from na 2 sio 3 and na 2 sialo 4 biodiesel from soybean oil reached 99% yield with 8 cycles 95%. In this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. Applications of waste cooking oil other than biodiesel. Upstream, mainstream, and downstream strategies for economizing biodiesel production were.
Biodiesel production from waste cooking oil using sulfuric. Life cycle assessment of biodiesel production from waste cooking oil in western australia abstract biodiesel derived from waste cooking oil wco is considered highly environmental sustainable since wco is a waste product which has been recycled to a transportation fuel in western australia. Overview of biodiesel production using waste oil the high viscosity vegetable oil must be chemically converted for it to operate properly in a diesel engine biodiesel conversion process does this caution. Biodiesel from waste vegetable oil a study on production and. Biodiesel is one of the available alternative fuels in the market. Production of biodiesel from vegetable oil youtube. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of inlet fluids were optimized.
Biodiesel production from waste oils sciencedirect. It is desirable as an alternative to petroleum fuel because it uses renewable resources that. If using waste vegetable oil, pour the waste oil into holding tank 1 waste oil tank i. Meera bai department of biotechnology and biochemical engineering sree buddha college of engineering, pattoor p. Biocatalytic production of biodiesel from vegetable oils. Catalysts used in this process are usually acids, base, and lipase. Biodiesel production from waste oils is an attractive option to produce biodiesel economically, but high free fatty acids ffa in waste oils are a serious bottleneck. Waste cooking oil wco can be processed into biodiesel as an alternative fuel to replace diesel. Feasibility study of biodiesel and waste vegetable oil at. Study the economic viability of biodiesel production of cooking oil in manaus. The values obtained from the biodiesel produced from waste vegetable oil are closely matched with the values of conventional diesel and it can. These includes linseed oil, palm seed oil, waste cooked vegetable oil, sunflower seed oil, cotton seed oil, cooking seed oil and animal fats 7, 8, 9.
The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the. Biodiesel from waste vegetable oil a study on production and performance s. Transesterification and production of biodiesel from waste. Biodiesel production from waste cooking oil carlos a. The term waste vegetable oil wvo refers to vegetable oil which has been used in food production and which is no longer viable for its intended use. Gashaw and others published production of biodiesel from waste cooking oil and factors affecting its formation. The monthly biodiesel production report provides data on operations of the u.
In this context, the cheaper waste cooking oils wcos are potential substitutes for vegetable oils in the production of biodiesel. Among all the operating conditions, methanol oil molar ratio, catalyst amount and calcinations. Production of biodiesel from waste cooking oil using cao. Pdf production of biodiesel from waste cooking oil and. Nov 21, 20 preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used. It is prepared from waste vegetable oils and animal fats by transesterification process. Less downstream processing is therefore needed for the mass production of biodiesel from domestic oil and its potential for industrial biodiesel production is higher. The oil used in biodiesel fuel production can be fresh clean oil or used waste oil that has been earlier used for frying as in this study. Kates b a department of chemical engineering, university of ottawa, ottawa, ont. Since lipase catalysts are much expensive, the usage of lipase in biodiesel.
Faculty of mechanical engineering noushirvani university of technology, 47148, iran. Unfortunately, commercial biodiesel production from refined vegetable oils leads to a dilemma. Production and life cycle assessment of biodiesel from three waste oils by ayoola ayodeji ayodele cugp050123 a thesis submitted in the department of chemical engineering to the school of post graduate studies as part of the requirements for the award of the degree of doctor of philosophy. Indias biodiesel processing capacity is estimated at 600,000 tons per year. It is considered a type of renewable energy, since it all comes from living plants and animals. Oil which has been used for cooking will required more of the reactive agents and methanol than fresh oil.
Among the alternatives as a vegetal raw material to extract the oil are. Introduction biodiesel refers to all kinds of alternative fuels derived from vegetable oils or animal fats. Life cycle assessment of biodiesel production from waste. Direct production of biodiesel at 65 c from waste oil by solid base was achieved. The production of biodiesel from used cooking oil begins with mixing raw materials of used cooking oil collected into one. Biodiesel production from waste sunflower cooking oil as an environmental recycling. The biggest impact within the process is associated with the use of methanol and the waste oil collection. Production of biodiesel from waste cooking oil using ultrasonic tubular reactor egi agustian a thesis submitted in fulfillment of the requirement for the award of the. Optimization of biodiesel production from waste cooking oil. Biodiesel in brazil comes from soy, beef tallow, and, in smaller quantities, cooking oil. Therefore, for the environmental concern and to reduce the biodiesel production cost, in this work, biodiesel was prepared from waste cooking oil wco which was transesterified using heterogeneous base catalyst.
Biodiesel from waste vegetable oil a study on production. Conversion of waste cooking oils into environmentally. The values obtained from the biodiesel produced from waste vegetable oil are closely matched with the values of. Waste vegetable oil is one of the sources of biodiesel and of all the other sources, it would be best in tropical countries. Lipase catalyzed production of biodiesel from soybean oil, sunflower oil, palm oil, kernel oil, coconut oil, rice bran oil, mixture of vegetable oils, grease and tallow oil, microbial oil, and waste oil containing vegetable oils have been reported in the past decades 1725. Waste cooking oil revolution in biodiesel production. Mcc alt fuels presents videos aimed at technicians who service vehicles that run on alternative fuels. Different techniques for the production of biodiesel from. A low cost vegetable oils, such as waste oil and nonedible oil, are considered as feedstocks, but their of concerns due tothelimited quantity of production3. Production and life cycle assessment of biodiesel from three. Sierra national university of colombia, colombia 1. In the present study biodiesel was synthesized from waste cook oil wco by threestep method and regressive analyzes of the process was done.
Therefore, for the environmental concern and to reduce the biodiesel production cost, in this work, biodiesel was prepared from waste cooking oil wco which was transesterified using. The impacts associated with the use of fossil fuels and climate change gas production is lower than that of the production of conventional fossil fuel diesel. On the basis of 100 lb of oil, the reaction mass balance with 100% xs methanol becomes. Lime as a cheap and abundant constructional material has shown good activity for catalyzing biodiesel production from waste frying oil. Also waste oils and fats used cooking oils are used as a good feedstock, its costs approaches half of the cost of virgin oil 4. In the present work, due to lack of data for optimum operating conditions and interaction effects, an optimization study was performed using response surface methodology. O, pandalam, kerala, india 690 529 muhammad nabeel department of biotechnology and biochemical engineering. Boyce bioenergy laboratory, programm of biotechnology, institute of biological sciences, faculty of science, university of malaya, kuala lumpur, malaysia abstract hossain, a. Nov 06, 2016 it is prepared from waste vegetable oils and animal fats by transesterification process. Energy analysis of biodiesel production from waste. Biodiesel production from waste cooking palm oil and environmental impact analysis 187 when vegetable oil or animal fat is reacted chemically with an alcohol to produce fatty acid alkyl esters transesterification somporn and shabbir, 2009. Quality characteristics of biodiesel produced from used cooking oil.
Small scale biodiesel production table of contents 1. The rubber seed oil rso is chosen as a potential nonedible vegetable oil for the production of biodiesel. If using clean oil, pour into holding tank 2 clean oil tank and proceed to section 4. Also, some biodiesel comes from waste oil and waste animal fat, that would otherwise be thrown away. This thesis includes a study regarding production of biodiesel from vegetable oils.
Nasa is testing biodiesel made from chicken fat to fuel their airplanes. Therefore, the use of waste cooking oil should greatly reduce the cost of biodiesel because waste oil is available at a relatively low price. All diesel fuel has a problem starting an engine in cold weather, but biodiesel has more of a problem. Extraction of biodiesel from waste vegetable oil clean.
The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. Production of biodiesel from waste vegetable oil publish. Study the economic viability of biodiesel production of. Biodiesel, a realistic fuel alternative for diesel engines springer2008. Regarding emissions, biodiesel is the only alternative fuel. The transesterification process was implemented to extract the biodiesel, and this process was optimized and standardized by selecting three different parameters. Do not use raw vegetable oil in an engine no matter what you read on the internet. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide. It is derived from biomass, which is one of the sources of renewable energy. Waste cooking oil revolution in biodiesel production longdom. One of the solutions to this issue is exploring lowcost, nonedible vegetable oil or animal fat such as waste oil for biodiesel production.
Hence, the recent focus rely on using waste cooking oil as the substantial feed stocks for biodiesel production. The conversion reached a value of above 50% in just 20 min. Pdf production of biodiesel from used cooking oil find, read and cite all the research you need on researchgate. This would not take away farmland that is used to grow food. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost.
The properties of the feedstock were determined using standard astm methods. A twostep transesterification process was used to produce bio diesel alkyl ester from high free fatty acid ffa waste cooking oil. Nov 27, 2015 domestic waste cooking oil produced biodiesel with a higher yield and better quality profile than biodiesel from restaurant waste cooking oil. Oils of high free fatty acids content can be converted into biodiesel via dual step transesterification process. Biodiesel simple english wikipedia, the free encyclopedia. Apr 19, 2017 in this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. Biodiesel production from waste cooking oils sciencedirect.
Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. Small scale biodiesel production feasibility report. Waste water from the fuel washing process approximately 1 gallon of water for every gallon of biodiesel glycerin is drained off at the end of the fuel production process approximately 1 gallon for every 3 gallons of biodiesel both the waste water and glycerin have small amounts of methanol in them. An improvement in biodiesel production from waste cooking oil by. Waste cooking oil is an interesting raw material, because it does not compete with food. In this chapter, focus will be given toward enzymatic biodiesel. Cooking oil is used in substantial quantity for food frying either in home, restaurants or in food industry. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor.
Recent strategy of biodiesel production from waste cooking. Biodiesel production from waste cooking oil intechopen. Make sure the valve v23 is in the horizontal position 3. It can be used to power an engine, usually for vehicles, including airplanes. Production of biodiesel from waste vegetable oil via km. Production of biodiesel using wco as the feedstock has been of growing interest for the last two decades. Biodiesel is a combustible fuel that is biodegradable and made from vegetable oil or animal fat. Recycling of waste cooking oils wco to biodiesel production.
Biodiesel is synthesized by direct transesterification. Biodiesel, as a promising source, can be prepared from waste frying oil in the presence of heterogeneous catalysts. The new process technologies developed during the last years made it possible to produce biodiesel from recycled frying oils comparable in quality to that of virgin vegetable oil biodiesel with an. In the first step, the oil is treated by an acid dissolved in methanol to reduce ffa content, whereas in the second step the pretreated oil is transesterified with methanol in. Production and life cycle assessment of biodiesel from. Biodiesel, waste vegetable oil, transesterification, optimization. Production of biodiesel fuel from cooking oil waste. Process optimization for biodiesel production from waste. The objective of the study was to carry out energy analysis of biodiesel production from waste groundnut oil wgo.
Overview of biodiesel production using waste oil the high viscosity vegetable oil must be chemically converted for it to operate properly in a diesel engine biodiesel conversion process does this. A twostep transesterification process was used to produce biodiesel alkyl ester from high free fatty acid ffa waste cooking oil. Preparation, characterization and application of zeolitebased catalyst for production of biodiesel from waste cooking oil maryam hassani 1, ghasem d najafpour. Utilization of waste cooking oil for biodiesel production. The production of biodiesel from waste vegetable oil offers a triplefacet solution. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. As large amounts of waste cooking oils are illegally dumped into rivers and landfills, causing environmental pollution 19, the use of waste cooking oil to produce biodiesel as petrodiesel substitute offers significant advantages because of the. While every reasonable effort has been made to ensure accuracy and completeness of the. Biodiesel is a liquid biofuel derived from lipids such as vegetable oils or animal fats reacting with alcohol through industrial processes of esterification and transesterification. In this study biodiesel was made from used cooking oil and methanol using the transesterification method with koh catalyst.
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